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Synonyms for Alternate (same or very similar meaning)

WordNet sense 1 (someone who takes the place of another person):
replacement, surrogate

WordNet sense 2 (allowing a choice):
alternative

WordNet sense 3 (occurring by turns; first one and then the other):
alternating

WordNet sense 4 (recurring in cycles):
cyclic, cyclical

WordNet sense 5 (be an understudy or alternate for a role):
understudy

WordNet sense 6 (reverse (a direction, attitude, or course of action)):
flip, flip-flop, interchange, switch, tack

WordNet sense 7 (go back and forth; swing back and forth between two states or conditions):
jump

WordNet sense 8 (do something in turns):
take turns


From the ODE community, based on WordNetadd/edit