Synonyms for Masterful (same or very similar meaning)
WordNet sense 1 (having or revealing supreme mastery or skill):
consummate, masterly, virtuoso, consummate
WordNet sense 2 (having or showing or requiring special skill):
skilled
WordNet sense 3 (able to deal authoritatively with affairs):
imperious
WordNet sense 4 (tending to domineer):
domineering
From the ODE community, based on WordNet
add/edit