WordNet sense 1 (create (as an entity)):

form, organise

WordNet sense 2 (form or join a union):

unionize, unionise

WordNet sense 3 (arrange by systematic planning and united effort):

devise, machinate, prepare, get up

WordNet sense 4 (plan and direct (a complex undertaking)):

direct, engineer, mastermind, orchestrate

WordNet sense 5 (bring order and organization to):

coordinate, coordinate