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Synonyms for Benevolent (same or very similar meaning)

WordNet sense 1 (showing or motivated by sympathy and understanding and generosity):
kindly, openhearted, sympathetic, good-hearted, large-hearted

WordNet sense 2 (having or showing a tender and considerate and helpful nature; used especially of persons and their behavior):
kind

WordNet sense 3 (generous in providing aid to others):
freehearted

WordNet sense 4 (willing to give and share unstintingly):
generous

WordNet sense 5 (generous in assistance to the poor):
beneficent, eleemosynary, philanthropic

WordNet sense 6 (full of love and generosity):
charitable


From the ODE community, based on WordNetadd/edit