Synonyms for Unmatched (same or very similar meaning)
WordNet sense 1 (of the remaining member of a pair, of socks e.g.):
odd, unpaired, unmated
WordNet sense 2 (either not matched or unsuitably matched):
mismatched
WordNet sense 3 (eminent beyond or above comparison):
matchless, nonpareil, one, peerless, unrivaled, unrivalled, unmatchable
WordNet sense 4 (such that comparison is impossible; unsuitable for comparison or lacking features that can be compared):
incomparable, uncomparable
From the ODE community, based on WordNet
add/edit