Synonyms for Cayenne (same or very similar meaning)
WordNet sense 1 (plant bearing very hot and finely tapering long peppers; usually red):
jalapeno, long pepper, Capsicum annuum longum, chilli pepper, cayenne pepper, chili pepper
WordNet sense 2 (ground pods and seeds of pungent red peppers of the genus Capsicum):
red pepper
From the ODE community, based on WordNet
add/edit