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Synonyms for Spitter (same or very similar meaning)

WordNet sense 1 (a person who spits (ejects saliva or phlegm from the mouth)):
expectorator

WordNet sense 2 (an illegal pitch in which a foreign substance (spit or Vaseline) is applied to the ball by the pitcher before he throws it):
spitball


From the ODE community, based on WordNetadd/edit